| Business | Phone |
| Goodwill Industries 101 Madison Square Dr, Madisonville 42431 | (270) 821-9045 |
| Habitat For Humanity 43 S Daves St, Madisonville 42431 | (270) 825-1539 |
| Historical Society Of Hopkins 107 Union St, Madisonville 42431 | (270) 821-3986 |
| Meals-On-Wheels Hopkins County 200 N Main St, Madisonville 42431 | (270) 821-9173 |
| Mothers Against Drunk Driving Po Box 1000, Madisonville 42431 | (502) 821-4141 |
| Pennyrile Allied Community Svc 136 Branch St, Madisonville 42431 | (270) 821-8114 |
| Retired Senior Volunteer Prgrm 136 Branch St, Madisonville 42431 | (270) 821-2252 |
| Salvation Army Thrift Store 805 Mccoy Ave, Madisonville 42431 | (270) 825-3682 |
| St Vincent De Paul Society 101 E Arch St, Madisonville 42431 | (270) 821-2159 |
| United Way 254 E Center St, Madisonville 42431 | (270) 821-3170 |
| Ymca 150 Ymca Dr, Madisonville 42431 | (270) 825-1254 |
| American Red Cross 124 N Scott St, Madisonville 42431 | (270) 821-6784 |
| Audubon Environmental 2000 College Dr, Madisonville 42431 | (270) 825-0998 |
| Big Brothers-Big Sisters 1 S Main St, Madisonville 42431 | (270) 821-0688 |
| Co-Operative Ministry-Hopkins 254 E Center St, Madisonville 42431 | (270) 825-4357 |
| Community Alternative 170 Bean Cemetery Rd, Madisonville 42431 | (270) 825-2557 |
| Family Advocacy Center Inc 36 Union St # B, Madisonville 42431 | (270) 825-1582 |