| Business | Phone |
| Friendship Ambulance Svc Inc 119 N Main St, Pennington Gap 24277 | (276) 546-4100 |
| Quality Care Ambulance Svc Inc Pennington Gap 24277 | (276) 546-6290 |
| Mercy Ambulance Svc 202 Woodway Rd, Pennington Gap 24277 | (276) 546-5500 |
| Liberty Ambulance Svc Inc 1320 W Morgan Ave, Pennington Gap 24277 | (276) 546-6911 |
| Highlander Ambulance Svc Pennington Gap 24277 | (276) 546-2500 |